Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80).

نویسندگان

  • Takatsugu Wakahara
  • Michio Yamada
  • Satomi Takahashi
  • Tsukasa Nakahodo
  • Takahiro Tsuchiya
  • Yutaka Maeda
  • Takeshi Akasaka
  • Masahiro Kako
  • Kenji Yoza
  • Ernst Horn
  • Naomi Mizorogi
  • Shigeru Nagase
چکیده

The (139)La NMR study of the exohedrally functionalized derivatives of La(2)@C(80) metallofullerene, La(2)@C(80)(Ar(2)Si)(2)CH(2) (: Ar = Mes, Mes = mesityl, : Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C(80) cage.

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عنوان ژورنال:
  • Chemical communications

دوره 26  شماره 

صفحات  -

تاریخ انتشار 2007